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Autonomous seawater partial pressure of carbon dioxide (pCO2) and pH time series from 40 surface buoys between 2004 and 2017 (NCEI Accession 0173932)

Published by NOAA National Centers for Environmental Information | National Oceanic and Atmospheric Administration, Department of Commerce | Metadata Last Checked: October 03, 2025 | Last Modified: 2018-06-22T00:00:00.000+00:00
This dataset consists of the data synthesis product files that include autonomous seawater pCO2, pH, sea surface temperature and salinity time series measurements from 40 surface buoys between 2004 and 2017. Ship-based time series, some now approaching over three decades long, are critical climate records that have dramatically improved our ability to characterize natural and anthropogenic drivers of ocean carbon dioxide (CO2) uptake and biogeochemical processes. Advancements in autonomous ocean carbon observing technology over the last two decades have led to the expansion of fixed time series stations with the added capability of characterizing sub-seasonal variability. Here we present a data product of 40 autonomous moored surface ocean pCO2 and pH time series established between 2004 and 2013. These time series characterize a wide range of seawater pCO2 and pH conditions in different oceanic (17 sites) and coastal (13 sites) regimes including coral reefs (10 sites). With well-constrained daily to interannual variability and an estimate of decadal variability, these data suggest the length of time series necessary to detect an anthropogenic trend in seawater pCO2 and pH varies from 8 to 15 years at the open ocean sites, 16 to 41 years at the coastal sites, and 9 to 22 years at the coral reef sites. Only two open ocean pCO2 time series, WHOTS in the subtropical North Pacific and Stratus in the South Pacific gyre, are longer than the estimated time of emergence, and deseasoned monthly means show anthropogenic trends of 1.9+/-0.3 µatm yr-1 and 1.6+/-0.3 µatm yr-1, respectively. In the future, it is possible that updates to this product will allow for estimating anthropogenic trends at more sites; however, the product currently provides a valuable tool in an accessible format for evaluating climatology and natural variability of surface ocean carbonate chemistry in a variety of regions.

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0173932 partial pressure of carbon dioxide - water carbon dioxide (CO2) gas analyzer chemical physical surface measurements time series moorings NOAA Pacific Marine Environmental Laboratory NOAA Pacific Marine Environmental Laboratory Global CO2 Time-series and Moorings Project (CDIAC) Caribbean Sea Indian Ocean North Atlantic Ocean North Pacific Ocean South Pacific Ocean oceanography DOC/NOAA/OAR/PMEL > Pacific Marine Environmental Laboratory, OAR, NOAA, U.S. Department of Commerce Ocean Acidification Program (OAP) Ocean Carbon and Acidification Data System (OCADS) Project High-Resolution Ocean and Atmosphere pCO2 Time-Series Measurements EARTH SCIENCE > OCEANS > OCEAN CHEMISTRY > CARBON DIOXIDE Mooring Time series Moorings SSS SST_C pCO2_air pCO2_sw pH_sw xCO2_air CO2 ANALYZERS > CO2 ANALYZERS MOORINGS Ala Wai BOBOA BTM CCE1 CCE2 CRIMP1 CRIMP2 Cape Elizabeth Cheeca Rocks Chuuk Chá bă (LaPush) Coastal MS Crescent Reef Dabob GAKOA Gray's Reef Gulf of Maine Hog Reef Iceland JKEO KEO Kaneohe Kilo Nalu Kodiak La Parguera M2 NH-10 Papa SEAK SOFS Stratus TAO110W TAO125W TAO140W TAO155W TAO165E TAO170W TAO8S165E Twanoh WHOTS OCEAN > ATLANTIC OCEAN > NORTH ATLANTIC OCEAN OCEAN > ATLANTIC OCEAN > NORTH ATLANTIC OCEAN > CARIBBEAN SEA OCEAN > INDIAN OCEAN OCEAN > PACIFIC OCEAN > NORTH PACIFIC OCEAN OCEAN > PACIFIC OCEAN > SOUTH PACIFIC OCEAN Indian Ocean North Atlantic Ocean North Pacific Ocean South Pacific Ocean

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